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«Anhydrous Ammonia Safety Data Sheet According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Revision Date: ...»

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Anhydrous Ammonia

Safety Data Sheet

According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Revision Date: August 2015 Version: 1.0

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY

Product Identifier

Product Name: Anhydrous Ammonia

Synonyms: Ammonia

Intended Use of the Product Not available

Name, Address, and Telephone of the Responsible Party Company El Dorado Chemical Company 4500 North West Avenue P.O. Box 231 El Dorado, AR 71731 T (870) 863-1400 – F (870) 863-1126 Emergency Telephone Number Emergency number : (870) 863-1400, (800) 424-9300 (CHEMTREC, 24 hours)

SECTION 2: HAZARDS IDENTIFICATION

Classification of the Substance or Mixture Classification (GHS-US) Flam. Gas 2 H221 Compressed gas H280 Acute Tox. 3 (Inhalation:gas) H331 Skin Corr. 1B H314 Eye Dam. 1 H318 STOT SE 3 H335 Aquatic Acute 1 H400 Aquatic Chronic 2 H411 Label Elements GHS-US Labeling

Hazard Pictograms (GHS-US) :

GHS04 GHS05 GHS06 GHS07 GHS09 Signal Word (GHS-US) : Danger Hazard Statements (GHS-US) : H221 - Flammable gas H280 - Contains gas under pressure; may explode if heated H314 - Causes severe skin burns and eye damage H318 - Causes serious eye damage H331 - Toxic if inhaled H335 - May cause respiratory irritation H400 - Very toxic to aquatic life H411 - Toxic to aquatic life with long lasting effects Precautionary Statements (GHS-US) : P210 - Keep away from heat, sparks, open flames, hot surfaces. - No smoking.

P260 - Do not breathe vapors, mist, spray, gas.

P264 - Wash hands, forearms, and other exposed areas thoroughly after handling.

P271 - Use only outdoors or in a well-ventilated area.

P273 - Avoid release to the environment.

P280 - Wear gloves, protective clothing, eye protection, face protection, respiratory protection.

P301+P330+P331 - IF SWALLOWED: rinse mouth. Do NOT induce vomiting.

P303+P361+P353 - IF ON SKIN (or ha

–  –  –

Most Important Symptoms and Effects Both Acute and Delayed General: Toxic if swallowed. Corrosive. Causes burns. May cause frostbite on contact with the liquid. Causes serious eye damage.

May cause respiratory irritation.

Inhalation: Toxic if inhaled. May cause respiratory irritation. Inhalation may cause immediate severe irritation progressing quickly to chemical burns.

Skin Contact: Corrosive. Causes burns. Contact with the liquid may cause cold burns/frostbite.

Eye Contact: Causes serious eye damage. Contact with the liquefied gas causes frostbite.

Ingestion: Contact may cause immediate severe irritation progressing quickly to chemical burns. Ingestion is likely to be harmful or have adverse effects.

Chronic Symptoms: Not available Indication of Any Immediate Medical Attention and Special Treatment Needed If exposed or concerned, get medical advice and attention.

SECTION 5: FIREFIGHTING MEASURES

Extinguishing Media Suitable Extinguishing Media: Use extinguishing media appropriate for surrounding fire.

Unsuitable Extinguishing Media: Do not use a heavy water stream. Use of heavy stream of water may spread fire. Do not use water directly on liquid ammonia.

Special Hazards Arising From the Substance or Mixture Fire Hazard: Flammable gas. Will burn in the range of 16-25% in air.

Explosion Hazard: May form flammable/explosive vapor-air mixture.

Reactivity: Thermal decomposition generates : Corrosive vapors. Toxic Gas. May be corrosive to metals.

Advice for Firefighters Precautionary Measures Fire: Exercise caution when fighting any chemical fire.

Firefighting Instructions: In case of leaking gas fire, eliminate all ignition sources if safe to do so. Leaking gas fire: Do not extinguish, unless leak can be stopped safely. Use water spray or fog for cooling exposed containers.

Protection During Firefighting: Do not enter fire area without proper protective equipment, including respiratory protection.

Hazardous Combustion Products: Corrosive vapors. Toxic fumes are released. Nitrogen oxides.

Other information: Do not allow run-off from fire fighting to enter drains or water courses. Use water spray to disperse vapors. Do not use water directly on liquid ammonia.

Reference to Other Sections Refer to section 9 for flammability properties.

SECTION 6: ACCIDENTAL RELEASE MEASURES

Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Use special care to avoid static electric charges. Eliminate every possible source of ignition. Keep away from heat/sparks/open flames/hot surfaces - No smoking. Do not allow product to spread into the environment. Do NOT breathe (vapors, mist, spray, gas). Do not get in eyes, on skin, or on clothing.

For Non-Emergency Personnel Protective Equipment: Use appropriate personal protection equipment (PPE).

Emergency Procedures: Evacuate unnecessary personnel.

For Emergency Personnel Protective Equipment: Equip cleanup crew with proper protection.

Emergency Procedures: Ventilate area.

Environmental Precautions Prevent entry to sewers and public waters. Avoid release to the environment.





Methods and Material for Containment and Cleaning Up For Containment: As an immediate precautionary measure, isolate spill or leak area in all directions. Stop the flow of material, if this is without risk. Use only non-sparking tools. Notify authorities if liquid enters sewers or public waters.

Methods for Cleaning Up: Clean up spills immediately and dispose of waste safely. Isolate area until gas has dispersed. Stop the source of the release, if safe to do so. Consider the use of water spray to disperse vapors. Isolate the area until gas has dispersed.

Ventilate and gas test area before entering. Contact competent authorities after a spill.

August 2015 EN (English US) 3/11 Anhydrous Ammonia Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

–  –  –

Materials for Protective Clothing: Chemically resistant materials and fabrics. Wear fire/flame resistant/retardant clothing.

Corrosion-proof clothing.

Hand Protection: Wear chemically resistant protective gloves. Insulated gloves.

Eye Protection: Chemical goggles or face shield.

Skin and Body Protection: Wear suitable protective clothing.

Respiratory Protection: Use a NIOSH-approved self-contained breathing apparatus whenever exposure may exceed established Occupational Exposure Limits.

Thermal Hazard Protection: Wear suitable protective clothing.

Other Information: When using, do not eat, drink or smoke.

–  –  –

SECTION 12: ECOLOGICAL INFORMATION

Toxicity Ecology - General: Very toxic to aquatic life with long lasting effects.

Ammonia (7664-41-7) LC50 Fish 1 0.44 mg/l (Exposure time: 96 h - Species: Cyprinus carpio) EC50 Daphnia 1 25.4 mg/l (Exposure time: 48 h - Species: Daphnia magna) LC 50 Fish 2 0.26 - 4.6 mg/l (Exposure time: 96 h - Species: Lepomis macrochirus) Persistence and Degradability Anhydrous Ammonia Persistence and Degradability May cause long-term adverse effects in the environment.

Bioaccumulative Potential Anhydrous Ammonia Bioaccumulative Potential Not established.

Ammonia (7664-41-7) Log Pow -1.14 (at 25 °C) Mobility in Soil Not available Other Adverse Effects Other Information: Avoid release to the environment.

SECTION 13: DISPOSAL CONSIDERATIONS

Waste Disposal Recommendations: Dispose of waste material in accordance with all local, regional, national, provincial, territorial and international regulations.

Additional Information: Handle empty containers with care because residual vapors are flammable.

Ecology – Waste Materials: This material is hazardous to the aquatic environment. Keep out of sewers and waterways.

–  –  –

US State Regulations Ammonia (7664-41-7) U.S. - California - SCAQMD - Toxic Air Contaminants - Non-Cancer Acute U.S. - California - SCAQMD - Toxic Air Contaminants - Non-Cancer Chronic U.S. - California - Toxic Air Contaminant List (AB 1807, AB 2728) U.S. - Connecticut - Hazardous Air Pollutants - HLVs (30 min) U.S. - Connecticut - Hazardous Air Pollutants - HLVs (8 hr) U.S. - Connecticut - Water Quality Standards - Acute Freshwater Aquatic Life Criteria U.S. - Connecticut - Water Quality Standards - Acute Saltwater Aquatic Life Criteria U.S. - Connecticut - Water Quality Standards - Chronic Freshwater Aquatic Life Criteria U.S. - Connecticut - Water Quality Standards - Chronic Saltwater Aquatic Life Criteria U.S. - Delaware - Accidental Release Prevention Regulations - Sufficient Quantities U.S. - Delaware - Accidental Release Prevention Regulations - Threshold Quantities U.S. - Delaware - Accidental Release Prevention Regulations - Toxic Endpoints U.S. - Delaware - Pollutant Discharge Requirements - Reportable Quantities U.S. - Florida - Essential Chemicals List U.S. - Idaho - Non-Carcinogenic Toxic Air Pollutants - Acceptable Ambient Concentrations U.S. - Idaho - Non-Carcinogenic Toxic Air Pollutants - Emission Levels (ELs) U.S. - Idaho - Occupational Exposure Limits - TWAs U.S. - Louisiana - Reportable Quantity List for Pollutants U.S. - Maine - Air Pollutants - Criteria Pollutants U.S. - Massachusetts - Allowable Ambient Limits (AALs) U.S. - Massachusetts - Allowable Threshold Concentrations (ATCs) U.S. - Massachusetts - Oil & Hazardous Material List - Groundwater Reportable Concentration - Reporting Category 1 U.S. - Massachusetts - Oil & Hazardous Material List - Groundwater Reportable Concentration - Reporting Category 2 U.S. - Massachusetts - Oil & Hazardous Material List - Reportable Quantity U.S. - Massachusetts - Oil & Hazardous Material List - Soil Reportable Concentration - Reporting Category 1 U.S. - Massachusetts - Oil & Hazardous Material List - Soil Reportable Concentration - Reporting Category 2 U.S. - Massachusetts - Right To Know List U.S. - Massachusetts - Threshold Effects Exposure Limits (TELs) U.S. - Massachusetts - Toxics Use Reduction Act U.S. - Michigan - Occupational Exposure Limits - STELs U.S. - Michigan - Polluting Materials List U.S. - Michigan - Process Safety Management Highly Hazardous Chemicals U.S. - Minnesota - Chemicals of High Concern U.S. - Minnesota - Hazardous Substance List U.S. - Minnesota - Permissible Exposure Limits - STELs U.S. - New Hampshire - Regulated Toxic Air Pollutants - Ambient Air Levels (AALs) - 24-Hour U.S. - New Hampshire - Regulated Toxic Air Pollutants - Ambient Air Levels (AALs) - Annual U.S. - New Jersey - Discharge Prevention - List of Hazardous Substances U.S. - New Jersey - Environmental Hazardous Substances List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - New Jersey - Special Health Hazards Substances List U.S. - New Jersey - TCPA - Extraordinarily Hazardous Substances (EHS) U.S. - New Jersey - Water Quality - Ground Water Quality Criteria U.S. - New Jersey - Water Quality - Practical Quantitation Levels (PQLs) U.S. - New Mexico - Precursor Chemicals U.S. - New York - Occupational Exposure Limits - TWAs U.S. - New York - Reporting of Releases Part 597 - List of Hazardous Substances U.S. - North Carolina - Control of Toxic Air Pollutants U.S. - North Dakota - Air Pollutants - Guideline Concentrations - 1-Hour

–  –  –

U.S. - North Dakota - Air Pollutants - Guideline Concentrations - 8-Hour U.S. - Ohio - Accidental Release Prevention - Threshold Quantities U.S. - Ohio - Extremely Hazardous Substances - Threshold Quantities U.S. - Oregon - Permissible Exposure Limits - TWAs U.S. - Oregon - Precursor Chemicals U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List U.S. - Pennsylvania - RTK (Right to Know) List U.S. - Rhode Island - Air Toxics - Acceptable Ambient Levels - 1-Hour U.S. - Rhode Island - Air Toxics - Acceptable Ambient Levels - 24-Hour U.S. - Rhode Island - Air Toxics - Acceptable Ambient Levels - Annual U.S. - Rhode Island - Water Quality Standards - Acute Freshwater Aquatic Life Criteria U.S. - Rhode Island - Water Quality Standards - Acute Saltwater Aquatic Life Criteria U.S. - Rhode Island - Water Quality Standards - Chronic Freshwater Aquatic Life Criteria U.S. - Rhode Island - Water Quality Standards - Chronic Saltwater Aquatic Life Criteria U.S. - Tennessee - Occupational Exposure Limits - STELs U.S. - Texas - Effects Screening Levels - Long Term U.S. - Texas - Effects Screening Levels - Short Term U.S. - Vermont - Permissible Exposure Limits - STELs U.S. - Virginia - Water Quality Standards - Acute Freshwater Aquatic Life U.S. - Virginia - Water Quality Standards - Acute Saltwater Aquatic Life U.S. - Virginia - Water Quality Standards - Chronic Freshwater Aquatic Life U.S. - Virginia - Water Quality Standards - Chronic Saltwater Aquatic Life U.S. - Virginia - Water Quality Standards - Public Water Supply Effluent Limits U.S. - Virginia - Water Quality Standards - Surface Waters Not Used for the Public Water Supply Effluent Limits U.S. - Washington - Permissible Exposure Limits - STELs U.S. - Washington - Permissible Exposure Limits - TWAs U.S. - Wisconsin - Hazardous Air Contaminants - All Sources - Emissions From Stack Heights 25 Feet to Less Than 40 Feet U.S. - Wisconsin - Hazardous Air Contaminants - All Sources - Emissions From Stack Heights 40 Feet to Less Than 75 Feet U.S. - Wisconsin - Hazardous Air Contaminants - All Sources - Emissions From Stack Heights 75 Feet or Greater U.S. - Wisconsin - Hazardous Air Contaminants - All Sources - Emissions From Stack Heights Less Than 25 Feet U.S. - Wyoming - Process Safety Management - Highly Hazardous Chemicals U.S. - Alaska - Water Quality Standards - Acute Aquatic Life Criteria for Fresh Water U.S. - Alaska - Water Quality Standards - Chronic Aquatic Life Criteria for Fresh Water U.S. - Alaska - Water Quality Standards - Acute Aquatic Life Criteria for Marine Water U.S. - Alaska - Water Quality Standards - Chronic Aquatic Life Criteria for Marine Water U.S. - Alaska - Ambient Air Quality Standards Canadian Regulations Anhydrous Ammonia WHMIS Classification Class B Division 1 - Flammable Gas Class A - Compressed Gas Class D Division 1 Subdivision A - Very toxic material causing immediate and serious toxic effects Class E - Corrosive Material Water (7732-18-5) Listed on the Canadian DSL (Domestic Substances List) inventory.



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